Becht’s Post

C(sp3)-heteroatom bond formation of alkyl germanes (-GeEt3) unlocked with electrochemistry. https://lnkd.in/eaZQWqts

https://lnkd.in/eEC8rt-R A nickel-catalyzed decarbonylative alkynylation of acyl fluorides with terminal silylethynes

https://lnkd.in/evsDwwSK A nickel-catalyzed decarbonylative alkynylation of acyl fluorides with terminal silylethynes

We are pleased to share our work on vapor-phase aldol condensation of biomass-derived 2,5-hexanedione to 3-methyl-2-cyclopentenone over yttrium zirconate (50YZrO) catalyst. Even though bare 50YZrO was deactivated during the catalytic process due to coke formation regardless of the reaction conditions, the modification with Ag and operation in H2 flow was proven effective in tackling this issue. The poisoning experiment using CO2, 2,6-, and 3,5-dimethylpyridine indicates that the aldol condensation utilizes the acid and base sites of the 50YZrO catalyst, suggesting that the aldol condensation proceeds via an acid-base concerted mechanism.  

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https://lnkd.in/e_aSKjps Direct α-C-H acylation of various alkenes with aroyl fluorides using NHC, sulfinate, and photoredox cooperative triple catalysis

SnF2 is a commonly used additive than SnCl2 and SnBr2 in both pure tin and mixed lead-tin-based halide perovskites PVs. In this study, we investigate how SnF2 compares to other SnX2 additives (X = F, Cl, Br) in terms of electronic and ionic defect properties in FASnI3 perovskite. #perovskite #thinfilm #solarcell #solarPV

https://lnkd.in/dhSNEbF A silver-catalyzed hydroalkylation of terminal alkynes with alkylboranes as coupling partners for an efficient synthesis of diastereopure Z-alkenes

Free Webinar: Enhancing Ethylene Production - Borouge's Success with Aspen GDOT™ Deployment 🚀 Join us on July 25 (Thursday, 9:00 AM EDT) for an insightful webinar with Santosh Kolipaka, Senior Specialist in Production Optimization, as he shares Borouge's remarkable results from deploying Aspen GDOT. In this session, you'll discover how Borouge was able to: 🔹 Improve total site ultimate yield by 0.4%, delivering $10M USD in additional benefits 🔹 Reduce total flaring intervals by 90% 🔹 Increase energy savings by optimizing ethane recycle rates and inventory management Learn how Aspen GDOT's dynamic optimization propelled Borouge to operational excellence in ethylene production. Don't miss this opportunity to gain valuable insights and ask questions. 👉 REGISTER NOW:  https://lnkd.in/di-tBkEu Looking forward to your participation! #Webinar #EthyleneProduction #AspenGDOT #OperationalExcellence #Optimization #EnergySavings