Francesca Fiorentini’s Post

Another, i.e. second part of redox reactions chapter. #electrochemistry #chemistry #highschoolchemistry #batteries https://lnkd.in/g4KPD4DV

New nanocatalysts or nanodrugs？

#MTCiting The hydrogenation of an aryl ketone in a gas–liquid flow reactor, catalyzed by catalytic static mixers and monitored by PAT, was executed. Varying reactor parameters elucidated the effect of different residence times and temperatures in a single experiment. https://okt.to/VHJ6RG

A new paper published! I am happy to share that our paper on the Influence of Diluent on Extraction Parameters of Systems for Separation Am(III) and Ln(III) Based on 1,10-Phenanthroline-2,9-Diamide was published today as a part of the Special Issue Advances in Coordination Chemistry 2.0 of Molecules MDPI! Big congratulations to the first author, Michail Gerasimov, and to everyone who contributed! Choosing the diluent is an important step in separation technology modeling. In this systematic study of extraction systems for f-element separation, the nature of the diluent is demonstrated to have a significant impact on the complex formation and extraction parameters of tetradentate N,O-donor diamide of 1,10-phenanthroline-2,9-dicarboxylic acid with Am(III) and Ln(III). Find out more about pros and cons of using different solvents for An(III)/Ln(III) separation in the paper!

And another, third part of redox reactions chapter. #electrochemistry #chemistry #highschoolchemistry #batteries #energy https://lnkd.in/gC2sHHNN

#MTCiting The hydrogenation of an aryl ketone in a gas–liquid flow reactor, catalyzed by catalytic static mixers and monitored by PAT, was executed. Varying reactor parameters elucidated the effect of different residence times and temperatures in a single experiment. https://okt.to/uY76yL

Redox reactions and oxidation state definition as an introduction to electrochemistry. #electrochemistry #chemistry #highschoolchemistry #batteries https://lnkd.in/gtSw23_J

https://lnkd.in/gYY28Q-K This study presents the development of a scalable continuous flow process for synthesizing a densely functionalized quinazoline organozinc intermediate for the KRAS G12C inhibitor Divarasib (GDC-6036). Initially, a cryogenic batch metalation process faced logistical challenges due to the instability of the quinazoline organomagnesium species above −60 °C. Investigation of reaction kinetics in batch mode, followed by process modelling, led to a practical, continuous flow approach. Addressing reactor fouling issues, a combination of plug flow and continuous stirred tank reactors was implemented in the final production system. Laboratory experiments successfully translated to a multikilogram scale, yielding excellent performance in subsequent atroposelective Negishi cross-coupling.

Excited to share our latest publication, on the electrochemical ammonia oxidation reaction (AOR) using NiOOH as a catalyst. In this study, we explored the complex dynamics of AOR on NiOOH using a variety of operando/in-situ characterization techniques, focusing on how the oxygen evolution reaction (OER) and dissolved oxygen influence the process. Check out the full article! https://lnkd.in/dNf5p52N #Electrochemistry #Catalysis #EnergyConversion

The application of nano -magnesium oxide in catalysts Nano -magnesium oxide is a material with good catalytic activity and stability. Its application in catalysts is mainly reflected in the following aspects: #magnesia #mgo #magnesiasupplier #chemicalsupplier #magnesiumoxide https://lnkd.in/eKzy7y7z